本列表收录铋的化合物,包含已有文献记载的化合物与原创研究。
格式:[化学式],[颜色],mp.[熔点,°C],bp.[沸点,°C],(dec)/dec.[分解温度],d[温度,°C].[密度,g·cm−3],{结构},[溶解性],[化学活性(仅限于常见物质,如空气、水)、毒性],[参考文献]
目录
1 金属间化合物和铋化物
2 铋的无机化合物
3 铋的有机盐
4 有机铋化合物
5 参考文献
5.1 文献
5.2 字母注释
金属间化合物和铋化物
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Li3Bi,[W]
LiBi,{CuAu},[W]
Na3Bi,{Na3As},[W]
NaBi,{CuAu},易氧化,易水解,[W]
K3Bi,{Na3As},[W]
NiBi,{NiAs},[W]
H3Bi,无色气体,室温下很快分解,[W]
铋的无机化合物
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BiF3,灰白粉末,mp.649,bp.900,d.5.3,[W]
BiOF,白色晶体,[W]
BiF5,无色晶体,mp.151,bp.230,d.255.4,和水剧烈反应,[W]
BiCl3,白色晶体,mp.233.5,bp.441,d.4.75,[W]
BiOCl,白色晶体,[W]
BiBr3,黄色晶体,mp.219,bp.462,d.5.72,[W]
BiOBr,白色晶体,[W]
BiI3,黑绿晶体,mp.408.6,bp.542,d.5.64,[W]
BiOI,砖红色晶体,dec.300,[W]
Bi2O3,黄色粉末,{a:单斜;δ:立方},[W]
Bi(OH)3,白色粉末,[W]
Bi2S3,灰色晶体或暗棕色粉末,dec.680,d.7.39,{Sb2S3},[W]
Bi2Se3,d.6.82,[W]
Bi2Te3,d.7.7,[W]
Bi(NO3)3·5H2O,无色晶体,易潮解,易水解,[W]
BiONO3,白色粉末,[E]
Bi2(SO4)3·nH2O(n=2或7),白色固体,[W]
BiPO4,难溶,[W]
Bi(ClO4)3·5H2O,[W]
Bi6O4(OH)4(ClO4)6·7H2O,晶体,d.4.277,{P21212},[1]
NaBiS2,[W]
KBiS2,[W]
Cs3Bi2I9,[W]
Cs2Bi0.5Sb0.5Cl6,{Fm3m, K2PtCl6}[2]
AgBiF6,[W]
(tBu2Sb)tBuPBi(tBuNAsNtBu)2(tBu为叔丁基,与Bi相连的原子加下划线),红色晶体,d.1.702,{P1},[3]
铋的有机盐
编辑
BiO(HCOO),d.5.82,[4]
BiOCH3COO,无色晶体,d.4.72,[4]
BiO(C2H5COO),白色粉末,d.4.40,[4]
BiO(C3H7COO),白色粉末,d.3.93,[4]
BiO(C4H9COO),白色粉末,d.3.56,[4]
有机铋化合物
编辑
Bi(CH3)3,无色液体,bp.110,d.2.3,[W]
Bi(C2H5)3,液体,bp.107,dec.150(爆炸),[W]
Bi(C6H5)5,紫色晶体,室温分解,[W]
Bi(C6H5)3,无色晶体,bp.78,d.1.59,[W]
[Bi(C6H5)4][B(C6H5)4],mp.228,[W]
参考文献
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文献
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↑ Sundvall, Bengt. Crystal structure of tetraoxotetrahydroxohexabismuth (III) perchlorate heptahydrate, Bi6O4(HO)4(ClO4)6.7H2O: an x-ray and neutron diffraction study. Inorganic Chemistry. 1983, 22 (13): 1906–1912. ISSN 0020-1669. doi:10.1021/ic00155a017.
↑ Day, Peter. Spectra and Constitution of Antimony(III) Antimony(V) Hexahalide Salts and Related Compounds. Inorganic Chemistry (American Chemical Society (ACS)). 1963, 2 (3): 452–456. ISSN 0020-1669. doi:10.1021/ic50007a006.
↑ Ritter, Christian; Weigend, Florian; Hänisch, Carsten. Synthesis of a Molecule with Five Different Adjacent Pnictogens. Chemistry – A European Journal. 2020, 26 (39): 8536–8540. ISSN 0947-6539. doi:10.1002/chem.202002279.
↑ 4.0 4.1 4.2 4.3 4.4 Aurivillius B. X-ray studies of bismuth oxide acetate, CH3COO·OBi and related compounds. Acta Chem Scand, 1955, 9: 1213-8.
字母注释
编辑
E:实验
W:无机化学丛书. 第四卷. 氮 磷 砷分族. 科学出版社